Product ID:ALODINE 600
MSDS Date:09/06/1990
FSC:8030
NIIN:00-057-2354
MSDS Number: BRQLS

HENKEL CORPORATION

32100 STEPHENSON HIGHWAY
MADISON HEIGHTS, MI 48071
US

Emergency Phone: 517-263-9430 800-424-9300(CHEMTREC)

Info Phone: 313-583-9300

Preparer: PRODUCT ACCEPTANCE OFFICE

Cage: DO342

HENKEL CORPORATION-EMERY GROUP

CINCINNATI, OH 45232 US

Telephone: 513-482-2297

Cage: DO342

CHROMIC ACID (SARA 313)

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: 30-40%

OSHA PEL 0.05 MG/M3 AS CR

ACGIH TLV: 0.05 MG/M3 AS CR

SODIUM FLUOBORATE

CAS: 13755-29-8

RTECS: ED2975000

Fraction By Weight: 40-50%

OSHA PEL 2.5 MG/M3 AS F

ACGIH TLV: 2.5 MG/M3 AS F

POTASSIUM FLUOZIRCONATE

CAS: 16923-95-8

RTECS: TT0875000

Fraction By Weight: 10-15%

OSHA PEL 2.5 MG/M3 AS F

ACGIH TLV: 2.5 MG/M3 AS F

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

POTASSIUM FLUORBORATE

CAS: 14075-53-7

RTECS: ED2800000

Fraction By Weight: 10-30%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

POTASSIUM FLUORZIRCONATE (CERCLA) LD50 ORAL MOUSE 98 MG/KG

CAS: 16923-95-8

RTECS: ZH7028400

Fraction By Weight: 1-10%

OSHA PEL 5 MG/M3 ZR/STEL 10

ACGIH TLV: 5 MG/M3ZR/STEL 10

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:CHRONIC: REPEATED/PROLONGED SKIN
CONTACT MAY CAUSE "CHROME SORES". LONG-TERM EXPOSURE CAN CAUSE
LIVER/KIDNEY DAMAGE & DERMATITIS. REPEATED/PROLONGED INHALATION OF
MIST MAY CAUSE ULCERATION & PERFORMAT ION OF THE NASAL SEPTUM.
CONTAINS FLUORIDES. EXPOSURE TO FLUORIDES OVER YEARS MAY CAUSE
FLUOROSIS.
Explanation of Carcinogenicity:SEE SUPPLMENTAL
Effects of Overexposure:EYES: EYE CONTACT MAY RESULT IN LOSS OF VISION
WITH SEVERE BURNS. SKIN: SKIN CONTACT IS CORROSIVE TO TISSUES.
INGESTION: INGESTION COULD RESULT IN TISSUE DESTRUCTION OF
DIGESTIVE TRACT & SEVERE IRRITA TION TO RESP TRACT. INHALATION:
INHALATION OF DUST CAN CAUSE DAMAGE TO MUCOUS MEMBRANES,
PERFORATION OF NASAL SEPTUM.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF ASTHMA,
ALLERGIES OR KNOWN SENSITIZATIONS TO CHROMIC ACID OR CHROMATES.
IRRITATION OF RESPIRATORY SYSTEM.

First Aid:EYES: IMMED FLUSH EYES W/WATER FOR AT LEAST 15 MIN WHILE
FORCIBLY HOLDING EYELIDS OPEN. GET MED AID. SKIN: FLUSH SKIN
THOROUGHLY W/WATER FOR AT LEAST 15 MIN. IF IRRITATION PERSISTS, GET
MED AID. INGES TION: DRINK LRG QUANT OF WATER. CORROSIVE. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, DRINK MORE WATER. GET MEDICAL
ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF BREATH DIFF GIVE
OXYGEN. GET MED AID

Flash Point:NONE
Extinguishing Media:WATER
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS (SCBA) AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VIOLENT REACTIONS MAY OCCUR WITH ORGANIC
MATERIALS AND REDUCING AGENTS.

Spill Release Procedures:TRANSFER ANY EXCESS TO A CLEAN POLYETHLENE
CONTAINER. TREAT THE RESIDUE WITH A DILUTE SOLUTION OF
METABISULFATE TO REDUCE THE CHROME.
Neutralizing Agent:NEUTRALIZE WITH LIME TO PH = 7-8.

Handling and Storage Precautions:DON'T GET IN EYES, ON SKIN OR
CLOTHING. FOR INDUSTRIAL USE ONLY. CONTACT WITH COMBUSTIBLE
MATERIAL MAY CAUSE FIRE. DON'T TAKE INTERNALLY.
Other Precautions:CLOTHING CONTAMINATED WITH CONTENTS OF THIS PACKAGE
IS DANGEROUSLY FLAMMABLE. IMMEDIATELY REMOVE & WASH CONTAMINATED
CLOTHING BEFORE REUSE. DO NOT BREATHE DUST. WASH THOROUGHLY AFTER
HANDLING.

Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR AS REQUIRED TO
PREVENT OVEREXPOSURE.
Ventilation:LOCAL EXHAUST. PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR
LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE OR POLYVINYL GLOVES
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD
Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING. EYE WASH
FACILITY & EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY.
Supplemental Safety and Health
THERE IS LAB EVIDENCE AQUEOUS SODIUM DICHROMATE ADMINISTERED DIRECTLY
INTO THE LUNG, AT THE HIGHEST TOLERATED DOSE, OVER LIFETIME OF
RATS, CAUSES A SIGNIFICANTLY INCREASED INCIDENCE OF LUNG CANCER. IT
IS EXPECTED THAT CHROMIC ACID WAS TESTED IN THE MANNER AS AQUEOUS
SODIUM DICHROMATE, IT WOULD GIVE SIMILAR RESPONSE.

HCC:C1
Solubility in Water:APPRECIABLE
Appearance and Odor:YELLOW TO ORANGE POWDER CONTAINING REDDISH-BROWN
CRYSTALS.

Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, REDUCING AGENTS, ALKALINE MATERIALS.
Hazardous Decomposition Products:HYDROGEN FLUORIDE
Conditions to Avoid Polymerization:EXCESSIVE HEAT

Waste Disposal Methods:CONTAINS CHROMIUM/FLOURIDE COMPOUNDS WASTE
TREATMENT & NEUT MAY BE REQUIRED PRIOR TO DISPOSAL. THIS CHEMICAL
HAZARDOUS WASTE AS DEFINED BY EPA HAZARDOUS WASTE & CONSOLIDATED
PERMIT REULATIONS. DISPOSE IN COMPLIANCE W/LOCAL, STATE, FEDERAL
REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.